Room temperature aldol reactions using magnetic Fe3O4@Fe(OH)3 composite microspheres in hydrogen bond catalysis.

Imidazole Functionalized Magnetic Fe3O4 Nanoparticles a Highly Efficient and Reusable Brønsted Acid Catalyst for the Regioselective Thiocyanation of Aromatic and Heteroaromatic Compounds at Room Temperature in Water:Ethanol

The Magnetically recoverable Fe3O4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (Fe3O4-IL-HSO4) were synthesized and used as efficient magnetic catalysts for the regioselective thiocyanation of aromatic and heteroaromatic compounds at room temperature in Water: Ethanol. This procedure provided the target thiocyanat...

Enantioselective direct aldol reactions catalyzed by L-prolinamide derivatives.

l-Prolinamides 2, prepared from l-proline and simple aliphatic and aromatic amines, have been found to be active catalysts for the direct aldol reaction of 4-nitrobenzaldehyde with neat acetone at room temperature. They give moderate enantioselectivities of up to 46% enantiomeric excess (ee). The enantioselectivity increases as the amide N-H becomes a better hydrogen bond donor. l-Prolinamides ...

Non-traditional hydrogen bond explanation of asymmetric catalysis of Mukaiyama aldol reactions by dinuclear zinc semi-crown ligands

Synthesis of the Fe3O4@SiO2@SiO2-Tb(PABA)3 luminomagnetic microspheres.

In this paper, we describe the synthesis and characterization of a luminomagnetic microspheres with core-shell structures (denoted as Fe3O4@ SiO2 @SiO2-Tb(PABA)3). The luminomagnetic microspheres were characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM),...

Amperometric Hydrogen Peroxide Biosensor Based on Immobilization of Hemoglobin on a Glassy Carbon Electrode Modified with Fe3O4/Chitosan Core-Shell Microspheres

Novel magnetic Fe(3)O(4)/chitosan (CS) microspheres were prepared using magnetic Fe(3)O(4) nanoparticles and the natural macromolecule chitosan. Then, using an easy and effective hemoglobin (Hb) immobilization method, an innovative biosensor with a Fe(3)O(4)/CS-Hb-Fe(3)O(4)/CS "sandwich" configuration was constructed. This biosensor had a fast (less than 10 s) response to H(2)O(2) and excellent...